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1 article(s) from Schmidt, Annette M

Hybrid biofunctional nanostructures as stimuli-responsive catalytic systems

Gernot U. Marten,
Thorsten Gelbrich and
Annette M. Schmidt

Beilstein J. Org. Chem. 2010, 6, 922–931, doi:10.3762/bjoc.6.98

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Graphical Abstract

Scheme 1: Synthesis of magnetic biocatalyst particles.

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Figure 1: Structures of comonomers employed in the synthesis of functional core–shell particles.

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Figure 2: TEM images of a) Fe₃O₄ nanoparticles electrostatically stabilized by citric acid; b) Fe₃O₄@P(M₁₀₀) ...

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Figure 3: a) Cloud point temperature T_c of Fe₃O₄@P(O_xM_y) in water in relation to molar fraction of MEMA χ_M,ex...

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Figure 4: a) Normalized magnetization loops of dispersions based on Fe₃O₄@CA in water (solid line), Fe₃O₄@CPS...

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Scheme 2: Reaction scheme of the enzymatic digestion of BAPNA catalyzed by magnetically labeled trypsin ( [Graphic 1] ).

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Figure 5: a) Cornish-Bowden diagram for the temperature-dependent kinetic data of trypsin activity, and b) Ea...

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Scheme 3: Proposed mechanism of catalytic activity after heating magnetic biocatalyst particles above T_c.

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Figure 6: a) Turnover number k_cat and b) Michaelis constant K_m of particle- immobilized trypsin vs free tryps...

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Published 16 Sep 2010

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